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inexact differential : ウィキペディア英語版
inexact differential

An inexact differential or imperfect differential is a specific type of differential used in thermodynamics to express the path dependence of a particular differential. It is contrasted with the concept of the exact differential in calculus, which can be expressed as the gradient of another function and is therefore path independent. Consequently, an inexact differential cannot be expressed in terms of its antiderivative for the purpose of integral calculations; i.e. its value cannot be inferred just by looking at the initial and final states of a given system. It is primarily used in calculations involving heat and work because they are path functions, not state functions.
== Definition ==
An inexact differential is commonly defined as a differential form d''x'' where there is no corresponding function ''x'' such that: x = \int \textx \,. More precisely, an inexact differential is a differential form that cannot be expressed as the differential of a function. In the language of calculus, for a given vector field ''F'', \delta F = F \, \textr is an inexact differential if there is no function ''f'' such that
: F = \nabla f
The fundamental theorem of calculus for line integrals requires path independence in order to express the values of a given vector field in terms of the partial derivatives of another function that is the multivariate analogue of the antiderivative. This is because there can be no unique representation of an antiderivative for inexact differentials since their variation is inconsistent along different paths. This stipulation of path independence is a necessary addendum to the fundamental theorem of calculus because in one-dimensional calculus there is only one path in between two points defined by a function.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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